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Note iron (Fe, Z=26) undergoes endothermic nuclear burning NOT exothermic nuclear burning. So trying to burn iron cools the iron core. At this point, electrons in the iron core find it energetically favorable to very rapidly bind with the protons (of the iron nuclei) via electron capture (p+e(-)→n+μ_e) to create neutrons. The rapid disappearance of the electrons and their degenerate electron gas pressure leads to an implosion. The implosion turns into an explosion because the creation of the neutrons releases neutrinos (specifically electron neutrinos which in this dense environment do interact significantly with matter) which push outward the outer layers of the star. The explosion is a, in fact, core collapse supernova.