c = sqrt(a**2-b**2)(see Wikipedia: Ellipse: Ellipse in Cartesian coordinates). Note c = 0 for circles.
e = c/a = sqrt(a**2-b**2)/a = sqrt[1-(b/a)**2] ,and so e = 0 implies c = 0 (i.e., a circle) and e = 1 implies c = a (i.e., a straight line).
r_per = a-c = a(1-e) and r_apo = a+c = a(1+e)
Now the standard definition of the mean orbital radius is
r_mean = r_per + r_apo = a ,
i.e., r_mean is just the semi-major axis.
So we see that orbital eccentricity is the maximum relative deviation of the radius of an elliptical orbit from the standard mean orbital radius.
Note that (100*e) % is the maximum relative deviation as a percentage.