- An element is a species of
atom.
Thus, in a sense, atom
is just the
microscopic
perspective on element.
So element
and atom can be used as
synonyms
in many contexts.
- The atoms
in the periodic table
are arranged in
a way that reflects their chemical properties and, more fundamentally,
their electronic configuration
or in more general perspective their
electronic structure.
Down the columns, the
atoms tend to have similar chemical properties.
Along the rows (AKA the periods),
the chemical properties tend to vary in a systematic way.
The whole set of trends in the
periodic table are called the
periodic trends
(see Wikipedia: Periodic trends).
- The
chemistry
of atoms
(taking quantum mechanics,
nuclear physics,
and electron behavior as givens)
is determined by the number of protons
in the atomic nucleus.
This number is called
the atomic number
(symbolized by Z).
In other words,
the atomic number
determines the
electronic configuration
and chemical behavior.
Examples:
1
proton gives
chemical element
hydrogen,
2
protons gives
chemical element
helium,
etc.
- Atoms
were NOT well understood or accepted
when the periodic table
developed in the 19th century
(Wikipedia: Periodic table: History).
In particular, number of protons
(i.e., atomic number) was NOT
understood and the early versions of the
periodic table
had the
elements
ordered by increasing
atomic mass which is
almost the order by
atomic number
(see Wikipedia: Periodic table:
Mendeleev's table).
- The arrangement in the
periodic table
has only a limited correlation with the nuclear properties
of the atomic nuclei.
Of course, there is the major correlation that
the atomic number is
that the number of protons.
- Atomic mass is essentially proportional
to the combined number of protons and
neutrons.
There are smaller mass effects due to the
additional mass
of the electrons and
mass reduction due to the
binding energy
of all the particles.
- Atoms with the same
number protons, but different numbers of
neutrons are
isotopes of each other.
The isotopes of an
atom are nearly identical chemically, but
can have very different nuclear properties.
Many isotopes are unstable to
radioactive decay.
The half-life
of a radioactive isotope
is a kind of mean life before
radioactive decay
of an atomic nucleus.
- Lead (Pb)
(atomic number
82)
is the highest atomic-number
element
with absolutely stable
isotopes:
Pb-204,Pb-207,Pb-208
and Pb-206
(see
Wikipedia: Lead;
List of elements by
stability of isotopes).
But many of the higher atomic-number
elements
have isotopes with
half-lives of billions of years,
and so are exist on Earth in nearly constant
abundances over human history,
Uranium (U)
(atomic number
92)
has the highest
atomic number among
primordial elements
(i.e., elements
that have existed since the formation of
Solar System:
Solar System age = 4.5682 Gyr
by a standard definition).
Its longest lived
isotope
is U-238 with
half-life
4.46 Gyr.
- Currently,
Oganesson (Og, element 118) has
the highest atomic number, but
like all the high atomic-number
elements, it
doesn't occur in observable nature and is only seen in minute quantities after
creation in particle accelerators.
Such elements
typically only survive for a fraction of a
second before
they undergo radioactive decay.
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