Lecture 5: Light and Matter:
Reading Messages from the Cosmos:
- How is energy stored in atoms?
- Energy level transitions: This is the
Grotrian diagram for
atomic hydrogen (H_I).
The common form of
hydrogen (H, Z=1) in terrestrial environments
is molecular hydrogen (H_2).
Of course,
atomic hydrogen (H_I)
Geissler tubes (AKA spectral tubes, discharge tube)
and both kinds and
ionized (H**(+) are
found in many places in outer space.
The Grotrian diagram are abstract
diagrams. It is not how
atoms look.
- How atoms look.
For how they look, see
Atomic file:
atom_gold.html
- grotrian diagrams:
see the files with name "grotrian_ ... ".
For example,
Grotrian diagram file:
grotrian_02_00_He_I.html.
- The energy levels
of the electrons
(i.e., the overall electronic state)
are discretized, they are NOT continuous.
Quantum mechanics dictates
that the energy levels are quantized.
- Because they are quantized, only certain
atomic transitions.
- spectra:
- continuous spectrum: from
dense substance.
- emission line spectrum:
from a dilute gas.
- absorption line spectrum:
from a dilute relatively cold gas
transmitting light from a dense relatively hot
dense substance.
The cold gas absorbs in lines rather
than emits.
- The study of line spectra
is spectroscopy
done with a
spectrometer (AKA spectroscope).
- Spectra file:
spectroscopy_videos.html.
- continuous spectrum: from
dense substance.
A continuous spectrum
from a substance or object all at one
temperature
is called blackbody radiation.
Incandescent light bulbs
produce blackbody radiation
to high accuracy/precision.
Two represenations of spectra:
- Image spectrum.
- Intensity spectrum.
- emission line spectrum:
from a dilute gas.
- absorption line spectrum:
from a dilute relatively cold gas
transmitting light from a dense relatively hot
dense substance.
The cold gas absorbs in lines rather
than emits.
- solar spectrum:
- Image representation:
Sun file:
solar_spectrum_image.html.
- Intensity representation:
Sun file:
solar_spectrum_graph.html.
Also logarithmic plot
Sun file:
solar_spectrum_graph_2.html.
- The line spectra
are the chemical fingerprints of
atoms and
molecules including their
ions.
This the atomic hydrogen (H_I)
Grotrian diagram again.
- The emission line spectrum for
the atomic hydrogen spectral series
for the
visible band (fiducial range 0.4--0.7 μm
= 400--700 nm = 4000--7000 Å).
- The absorption line spectrum for
the atomic hydrogen spectral series
for the
visible band (fiducial range 0.4--0.7 μm
= 400--700 nm = 4000--7000 Å).
- The emission line spectra
for neutral atomic
helium (He, Z=2),
sodium (Na, Z=11), and
neon (Ne,Z=10).
- The emission line spectrum
from an mixture of gases
has a superposition of
individual species
emission line spectra.
- solar spectrum:
- Image representation:
Sun file:
solar_spectrum_image.html.
- Intensity representation:
Sun file:
solar_spectrum_graph.html.
Also logarithmic plot
Sun file:
solar_spectrum_graph_2.html.
- molecules:
rotational spectra,
vibronic spectra,
Rotational-vibrational spectroscopy,
and
electronic spectra.
- absorption lines: D
in both image and intensity representations of
a spectrum.
- B.
- A.
- temperatures of
stars
and planets:
photosphere effective temperaturem
Wien's law temperature,
effective temperature,
and
color temperature.
- thermal radiation
and blackbody radiation.
- Blackbody file:
blackbody_spectra.html.
- A: "a blue star."
- B: "People only emit light that is invisible to our eyes."
See Blackbody file:
stefan_boltzmann_law_logarithmic.html.
- What is the this object:
Its spectrum
has two components
of approximate
blackbody radiation:
hotter one with T &cong 6000 K from
Wien's law;
with the colder one at 225 K ≅ -48 C from
Wien's law.
The Earth has
two components
of approximate
blackbody radiation.
How is this possible?
- A carbon dioxide (CO_2)
atmosphere maybe.
You really CANNOT tell abundances from
line spectra
without other information.
- emission lines
in the
ultraviolet band (fiducial range 0.01--0.4 μm).
Maybe hot dilute gas.
But maybe non-thermal excitation like the
aurora.
- OK, it might look red compared to
sunlight
- Mars: The Red Planet:
Mars file:
mars_full.html.
Actually, Mars colors are tricky.
The shown
spectrum is from
space.
From the ground,
Some Mars spectra taken with Alpy600: colors of the planet+filters use
Mars is even redder
and has telluric lines:
absorption lines
from the Earth's atmosphere.
- Doppler effect
and relativistic Doppler effect:
The non-relativistic Doppler effect
applies to
sound waves
because the
speed of sound ≅ 343 m/s (T = 20 C at ordinary
pressures) <<
vacuum light speed c = 2.99792458*10**8 m/s
(exact by definition) ≅ 3*10**8 m/s = 3*10**5 km/s ≅ 1 ft/ns.
- Waves file:
wave_propagation.html which
can be used to explicate the basic
Doppler effect.
- Waves file:
doppler_effect_sonic.html
which can be used to explicate
sonic boom.
- Waves file:
doppler_effect_videos.html.
- But light because it moves
at the speed of light
(though often at less than the
vacuum light speed c = 2.99792458*10**8 m/s
(exact by definition) ≅ 3*10**8 m/s = 3*10**5 km/s ≅ 1 ft/ns)
always has the
relativistic Doppler effect
though we just say
Doppler effect when we know what
we mean.
Qualitatively, the
non-relativistic Doppler effect
and
relativistic Doppler effect
are much the same, but
formulae are different.
- But a key difference is the
non-relativistic Doppler effect
in general depends on three speeds:
the velocity of the source, the
velocity of the observer, and the
phase speed
(i.e., wave speed) relative to the
transmission medium.
The relativistic Doppler effect
for light
in vacuum only
depends on the relative
line of sight
velocity
of the source and observer.
- The Doppler effect
is best observed in
line spectra since
you know the line wavelengths
unshifted from the laboratory
and you can recognize their pattern even when
Doppler shifted.
With continuous spectra
how do you know if their is a
Doppler shift at all?
- The
transverse Doppler effect
is a relativistic effect and is too small to observe almost always.
- A.
- macroscopic
Doppler line broadening.