Most nature-definingly for stars, it should be a log-log plot of luminosity versus photospheric temperature.
However, neither of these quantities are direct observables, and so proxies are often used as described below.
The HR diagram allows an empirical classification of stars for which a theoretical understanding has developed.
The hydrogen burning
is nuclear burning, NOT
chemical burning.
Nuclear burning
it is the analogous process in
nuclear physics
to
chemical burning.
However, nuclear burning
is of order 10**6 more energetic than
chemical burning.
So we say
full stellar classification
consists of giving both
spectral type
and
luminosity class.
This is a useful shorthand.
Context tells you when it is used.
Stars
are really unique individuals looked at closely.
Also stars of the
same "full"
stellar classification
can have vary from each other in other ways: these variations are
are sometimes important.
In the case of photospheric temperature,
the temperature decreases to the right---one of the
old wrong-way traditions of astronomy.
When photospheric temperature
is the horizontal axis, it is usually in the form of logarithmic
photospheric temperature
(see
Wikipedia: HR Diagram: Forms of diagram).
V band
is the passband filter most often used to
characterize the brightness of stars.
It has central wavelength λ_central = 0.551 μm
and FWHM Δλ = 0.088 μm.
The V band mostly measures
in the green color band (∼ 0.495--0.570 μm),
yellow color band (∼ 0.570--0.590 μm),
orange color band (∼ 0.590--0.620 μm),
and red color band (∼ 0.620--0.740 μm).
Also magnitude runs the
wrong way---higher number is dimmer, lower number is brighter---it seemed like
a good idea to Ptolemy (c. 90--c. 168 CE)---just
accept it.
A change of 5 magnitudes
is defined to be exactly a change of 100 in
luminosity,
(i.e., energy output per unit time).
This means that a change of 1
magnitude
is a change in luminosity of
100**(1/5) = 10**(2/5) = 2.5118864 ... ≅ 2.512.
Absolute V magnitude
measures energy only in the
V band
whereas luminosity is
energy from the whole
electromagnetic spectrum.
To go from absolute V magnitude
to luminosity requires
a bolometric correction
which is dependent on the type of
star.
However, an approximate fiducial transformation is---as one would expect from the discussion above---that
a 1 mag increase corresponds
to a decrease in luminosity
of a factor of
100**(1/5) = 10**(2/5) = 2.5118864 ... ≅ 2.512
and
that a 5 mag increase corresponds
to a decrease in luminosity
of a factor of 100.
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In fact, usually when people say
spectral type, they
mean spectral type and
luminosity class
together.
The "full" stellar classification
by
spectral type
and
luminosity class
does NOT completely uniquely specify a star
since in both classification schemes
the categories are only fairly narrow BINS, and
NOT very fine BINS.
They can vary in rotation and composition and other ways.
There are, in fact, other classification schemes to
handle some of the these cases
(see Wikipedia: stellar classification).
But those schemes are beyond our scope.