Jim Selser's Research Interest
Jim Selser and his group (two grad students, one postdoc) will study macromolecular systems. Presently, the structure and dynamic behavior of a polymer melt (macromolecular liquid) are being investigated using laser light scattering, rheometry and thermal analysis. The particular polymer being studied is poly(ethylene oxide), a polymer with a variety of practical uses. Of particular interest is the use of solutions of PEO melts containing dissolved lithium salts for use as "plastic battery" polymer electrolytes.
It turns out that even molten PEO is very hygroscopic, which can be a serious problem since even small amounts of water in PEO can have dramatic and undesirable effects. The student project for Summer 2004 will be to design and fabricate a chamber assembly for PEO melt samples which will then be used to study the effects on these melts of temperature and moisture under carefully controlled conditions.
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